SERS assay for epigenetic markers

Investigator: Saraswati Sukumar
Johns Hopkins School of Medicine

Investigator's profile

The Sukumar laboratory has performed seminal studies to unravel the roles of members of the HOX gene family in breast cancer progression [1] and pioneered the application of intraductally administered therapeutic agents to treat preneoplastic ductal lesions [2]. Her lab's discovery of novel methylated genes through first ever SAGE analysis of breast cancer followed by the development of multiplexed quantitative PCR assays set the foundation for monitoring tumor burden based on aberrantly methylated genes [3].

Significance

Figure 1: Assessment of 10-gene methylated marker panel in sera acquired from recurrent metastatic stage IV breast cancer patients. A) Box plot showing that cancer sera display significantly higher median cumulative methylation than normal sera B) Plot of cumulative methylation index (CMI) values for individual samples, where each colored segment represents the methylation index for an individual gene. C) Frequency of methylation for individual biomarkers in the 10-gene panel. Scatter plot depicts gene methylation intensity (y-axis, methylation index) for individual genes (x-axis) in the test set for normal and cancer sera. The Mann-Whitney P values are shown below each plot.

In the clinical management of breast cancer patients, hypermethylation in circulating cell-free DNA is of great interest in various contexts: first, when primary tumor or metastatic tissue samples are not available; second, for surveillance of asymptomatic cancer survivors; third, for evaluating response to systemic therapies in the neoadjuvant, adjuvant and metastatic settings; and finally, as potential diagnostic surrogates. Hence, methods that can quantitate multiple methylated gene markers at exceedingly low concentrations from small volumes with easily achievable sample processing requirements are highly desirable.

Approach

Because the levels of DNA shed are so low, especially in patients with no symptoms of metastatic disease, this collaborative project proposes to develop an ultrasensitive and multiplexed platform featuring surface-enhanced Raman spectroscopy (SERS) and highly selective single base extension reaction [4]. Using DNA methylation analysis, the Sukumar lab has characterized a 10-gene panel composed of seven novel and three known breast cancer hypermethylated markers (Fig. 1). The panel displayed >90% sensitivity and 100% specificity when tested in sera of metastatic breast cancer patients. A decrease in median serum DNA methylation levels was observed in the selected genes in patients with stable disease or a therapeutic response but not in patients with progressive disease. Leveraging this panel, the LBRC proposes to develop a SERS assay by extending their recently established breast tumor antigen detection method. The benchmarks for the proposed assay development will be the sensitivity, specificity and reproducibility offered by the cMethDNA assay.

Research plans

To enable ultrasensitive and multiplexed detection of methylated breast cancer markers, LBRC will develop a SERS assay by extending Sukamar's recently established breast tumor antigen detection method. Working with the Sukumar lab, we will use the sera already acquired at different time points from the metastatic breast cancer patients undergoing chemotherapy to demonstrate the feasibility of our new SERS assay in monitoring response to breast cancer therapy.

Summary

LBRC aims to develop rationally tailored plasmonic nanoprobes, and a new method for sensing of gene-specific (rather than genome-wide) methylation for breast cancer detection. The Sukumar lab is also embarking on analyzing the prognostic and predictive utility of cMethDNA, CA 27.29 antigen and CTC, using prospectively collected serum. To support this effort, LBRC will develop an integrated SERS-based platform for detecting circulating tumor antigens and methylated markers. Furthermore, the LBRC will also design and engineer SERS nanoprobe constructs to assist our investigator in their study of microRNAs (miRNA) to reveal tumor-specific alterations.

References

  1. "THOXA5 acts directly downstream of retinoic acid receptor beta and contributes to retinoic acid-induced apoptosis and growth inhibition," Cancer Research, Vol. 67, Issue 17, Sep 2007. [ Pubmed ]
  2. "Preclinical and clinical evaluation of intraductally administered agents in early breast cancer," Science Translational Medicine, Vol. 3, Issue 106, Oct 2011. [ Pubmed ]
  3. "Quantitative multiplex methylation-specific PCR assay for the detection of promoter hypermethylation in multiple genes in breast cancer," Cancer Research, Vol. 64, Issue 13, pp. 4442-52, July 2004. [ Pubmed ]
  4. "Fluorescent Conjugated Polyelectrolyte as an Indicator for Convenient Detection of DNA Methylation," J Am Chem Soc., Vol. 130, Issue 34, pp. 1338-11343, Aug 2008. [ Pubmed ]